Sie befinden Sich nicht im Netzwerk der Universität Paderborn. Der Zugriff auf elektronische Ressourcen ist gegebenenfalls nur via VPN oder Shibboleth (DFN-AAI) möglich. mehr Informationen...
•Monolayer WSe2 was obtained by a copper-assisted chemical vapor deposition method.•WSe2 triangles exhibit single-crystalline nature and possess high crystal quality.•Cu atoms preferentially occupy upper active sites, leading to a monolayer growth.•The Cu-assisted growth method offers a new strategy for the monolayer synthesis.
In this work, we demonstrate the controllable synthesis of high-quality WSe2 monolayers via a copper-assisted chemical vapor deposition method. The structure characterizations confirm that the as-grown WSe2 crystals by introducing Cu powder exhibit monolayer thickness and high crystalline quality. Most importantly, theoretical calculation reveals that Cu atoms could easily occupy the active sites above the monolayer WSe2 surface, consequently forming a self-limited growth. The Cu-assisted growth method broadens the scope of the 2D growth of other TMD materials, and also provides more application potential in 2D electronics.