Details

Autor(en) / Beteiligte

• Kubus, Mariusz
• Heinicke, Robert
• Ströbele, Markus
• Enseling, David
• Jüstel, Thomas
• Meyer, H.-Jürgen

Titel

Synthesis of new structurally related cyanamide compounds LiM(CN2)2 where M is Al3+, In3+ or Yb3

Ist Teil von

• Materials research bulletin, 2015-02, Vol.62, p.37-41

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2015

Quelle

ScienceDirect

Beschreibungen/Notizen

• [Display omitted] •New cyanamide compounds LiM(CN2)2 where M is Al3+, In3+ or Yb3+.•New luminescent material LiIn(CN2)2:Tb3+.•Reduction in efficiency of luminescence with temperature increase. New ternary cyanamide compounds isostructural to LiY(CN2)2 were obtained by solid state metathesis reaction. The crystal structure of LiAl(CN2)2 was determined by single crystal X-ray diffraction, the structures of LiIn(CN2)2 and LiYb(CN2)2 were solved from X-ray powder diffraction data. Photoluminescence properties of Tb3+-doped LiIn(CN2)2 are reported too.