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Details

Autor(en) / Beteiligte
Titel
The impact of the Au/Ag ratio on the photocatalytic activity of bimetallic alloy AuAg nanoparticle-decorated ZnO nanorods under UV irradiation
Ist Teil von
  • The Journal of physics and chemistry of solids, 2021-07, Vol.154, p.110038, Article 110038
Ort / Verlag
Elsevier Ltd
Erscheinungsjahr
2021
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
  • Zinc oxide (ZnO) is a semiconducting material that is widely used in photocatalytic applications. Unfortunately, due to the rapid electron-hole pair recombination, the photocatalytic efficiency of ZnO is very low. Creating new nanocomposites of ZnO with bimetallic nanoparticles (NPs) is a promising research effort. In this study, the AuAg NPs were deposited onto ZnO nanorods (NRs) grown on a glass substrate using one-pot hydrothermal with five different molar ratios of the HAuCl4 and AgNO3 precursors (1:0, 3:1, 1:1, 1:3, and 0:1). The result shows that the photocatalytic dye degradation performance of ZnO/Au1Ag3 is comparable to that of ZnO/Au (49–50%, k = 0.00709 min−1), which is twice as efficient as the performance of the pristine ZnO (25%, k = 0.00254 min−1). The high number of deposited Au1Ag3 NPs roughened the surface of the nanocomposites, and their role in inhibiting the exciton recombination rates may have a significant effect on enhancing the photocatalytic activity of pristine ZnO. •AuAg NPs were deposited onto ZnO NRs with different molar ratios of the HAuCl4 and AgNO3 precursors.•The photocatalytic performance of ZnO/Au1Ag3 is comparable to that of ZnO/Au.•The high number of deposited Au1Ag3 NPs roughened the surface of the nanocomposites.•The Au1Ag3 NPs inhibit the exciton recombination rates and generates more free electrons and holes.
Sprache
Englisch
Identifikatoren
ISSN: 0022-3697
eISSN: 1879-2553
DOI: 10.1016/j.jpcs.2021.110038
Titel-ID: cdi_crossref_primary_10_1016_j_jpcs_2021_110038

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