Details

Autor(en) / Beteiligte

• Emam, Hossam E.
• Abdelhameed, Reda M.
• Ahmed, Hanan B.

Titel

Adsorptive Performance of MOFs and MOF Containing Composites for Clean Energy and Safe Environment

Ist Teil von

• Journal of environmental chemical engineering, 2020-10, Vol.8 (5), p.104386, Article 104386

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2020

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• [Display omitted] •The review summarized the vital role of MOF exploitation in safe environment and clean energy.•MOFs are characterized by large surface areas and ultrahigh porosity with micro- to mesoporous regime.•Storing of gases as alternative fuel and adsorption of toxic gases onto MOF were concluded.•Reported researches for ultra-filtration of liquid fuel by MOFs in the recent works was presented.•The adsorption capacity depended on the porosity, H-bonding and with minor relevant on the π- π interaction. Combustion of fossil fuel harmfully effects on environment via releasing of sulphur- and nitrogen-containing contaminants as the hazardous chemicals. Liberation of CO2, NO2 and SO2 as harmful toxic gases within combustion of liquid fuel was 164 000, 448 and 1122 pounds per billion BTU. Therefore, for safe environment and for economic factors related to energy costs, storing of H2, O2, N2, and CH4 gases as preferably applied as alternative fuel, in aaddition to, ultra-filtration of liquid fuel were extensively reported as considerable researching points of study. The most recent applicable materials as highly porous compounds is the porous coordination polymers or more commonly ascribed as metal-organic frameworks (MOFs), which is mainly constructed from organic ligands (referred to linkers) and metal centers that serve as bridge. MOFs are specially characterized by large surface area and ultrahigh porosity with pore size ranging from the micro- to mesoporous regime, resulting in superior adsorption performance. The current review brightens the vital role of MOF exploitation in safe environment and clean energy. Herein we summarized the most common synthetic techniques for MOFs, functionalized MOFs and MOF containing composites, and the recent researching reports interested in toxic gases capturing, energy storage and ultra-filtration of liquid fuel via adsorption technique.