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•Preparation of TiO2/RGO nanocomposite by annealing method at 180 °C.•Employing TiO2/RGO nanocomposite toward sensing methanol, ethanol and acetone vapors with different ppm.•Observation an excellent response for ethanol detection even in low gas volume.
Reduced graphene oxide and metal oxides derivatives are introduced as relatively benign materials for improving gas sensors' performance as exemplified by the synthesis of TiO2/GO nanocomposite via ultrasonication, and then the assembly of RGO adorning TiO2 nanoparticles (NPs) (TiO2/RGO) is accomplished using the thermal annealing method. The characterization of the as-fabricated sample indicated that irregular shaped TiO2 NPs with size of 26 nm covered the RGO nanosheets. The optical band gap measurement indicated the values of 3.19, 2.1 and 2.5 eV for TiO2, GO and TiO2/RGO samples, respectively. The ensued nanocomposites are then deployed for the gas sensing response of three common organic vapors of ethanol, methanol, and acetone with concentrations of 20, 40, 60, 80, 100 ppm, at ambient temperature. The TiO2/RGO sensor relatively exhibited an excellent response (3–4 times) for ethanol detection. These results indicated that the application of TiO2/RGO can help assist in the evolvement of portable gas sensing devices endowed with the capability to detect common place organic vapors.