Details

Autor(en) / Beteiligte

• Sen, Betül
• Kuzu, Sultan
• Demir, Enes
• Onal Okyay, Tuğba
• Sen, Fatih

Titel

Hydrogen liberation from the dehydrocoupling of dimethylamine–borane at room temperature by using novel and highly monodispersed RuPtNi nanocatalysts decorated with graphene oxide

Ist Teil von

• International journal of hydrogen energy, 2017-09, Vol.42 (36), p.23299-23306

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2017

Link zum Volltext

Quelle

Elsevier ScienceDirect Journals Complete

Beschreibungen/Notizen

• Addressed herein, we reported the fabrication of the graphene oxide (GO) supported monodispersed ruthenium–platinum–nickel (RuPtNi) nanomaterials (3.40 ± 0.32 nm) to be utilized as a catalyst in the process of dimethylamine borane (DMAB) dehydrogenation. The nanoparticles were fabricated through the ultrasonication method by co-reducing the Ru3+, Pt2+ and Ni2+ cations and then the nanomaterials were characterized by X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), inductively coupled plasma optical emission spectrometry (ICP-OES), and X-ray photoelectron spectroscopy (XPS). The fabricated nanomaterials showed outstanding efficiency and remarkable reusability in addition to their record catalytic activity at low temperatures and with extreme low concentrations. They had a significantly high turnover frequency (TOF) (727 h−1) and low activation energy (Ea) (49.43 ± 2 kJ mol−1) for DMAB dehydrocoupling. To the best of our knowledge, RuPtNi@GO NPs become a very promising candidate as the best catalyst ever. •Highly monodisperse Ruthenium–Platinum–Nickel Alloy Nanoparticles decorated by reduced graphene oxide (RuPtNi@GO).•The discovery of a remarkable DMAB dehydrocoupling catalyst.•The record TOF value of RuPtNi@GO for dimethylamine–borane dehydrogenation.•Thanks to the ultrasmall sizes, monodispersity and high metallic ratio of Ru, Pt and Ni.