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Preparation and properties of polyimide/graphene oxide nanocomposite films with Mg ion crosslinker
Ist Teil von
European polymer journal, 2012-08, Vol.48 (8), p.1394-1405
Ort / Verlag
Kidlington: Elsevier Ltd
Erscheinungsjahr
2012
Link zum Volltext
Quelle
Access via ScienceDirect (Elsevier)
Beschreibungen/Notizen
[Display omitted]
► Polyimide(PI)/graphene oxide(GO) hybrid films were prepared by cross-linking using Mg ions. ► The PI/GO nanocomposites showed enhanced tensile properties compared to pristine PI. ► Mg ions can bond between the oxygen functional groups and carboxylate groups of GO and PAA. ► The nanocomposites may have potential use as dielectric materials.
Polyimide(PI)/graphene oxide(GO) nanocomposite films were prepared by chemical cross-linking using small amounts of divalent Mg ions. The PI/GO nanocomposites showed enhanced tensile properties compared to pristine PI due to the presence of exfoliated GO in the PI matrix as well as crosslinking between poly(amic acid) (PAA), which is a precursor of PI, and GO by Mg ions. The hydrogen bonds between PAA and GO suppressed the phase separation between PI and GO, and small amounts of Mg ions can bond between the oxygen functional groups and carboxylate groups of GO and PAA.