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High capacitance at a high charge–discharge current density of 50
mA/cm
2 for a new type of electrochemical supercapacitor cobalt sulfide (CoS
x
) have been studied for the first time. The CoS
x
was prepared by a very simply chemical precipitation method. The electrochemical capacitance performance of this compound was investigated by cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge–discharge tests with a three-electrode system. The results show that CoS
x
has excellent electrochemical capacitive characteristic with potential range −0.3
∼
0.35
V (versus SCE) in 6
M KOH solution. Charge–discharge behaviors have been observed with the highest specific capacitance values of 475
F/g at the current density of 5
mA/cm
2, even at the high current density of 50
mA/cm
2, CoS
x
also shows the high specific capacitance values of 369
F/g.