Details

Autor(en) / Beteiligte

• Bai, Yanying
• Guo, Weichao
• Zhao, Qingxin
• Shen, Heying
• Qiu, Yongxiang

Titel

Strength formation mechanism and curing system optimization of low-carbon cementitious materials prepared by synergistic activation of multiple alkaline solid wastes

Ist Teil von

• Construction & building materials, 2023-10, Vol.402, p.132931, Article 132931

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2023

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• •Curing at 80 °C for 8 h was proved to be the optimal high temperature curing method.•The optimum ratio of CS:SR:RM:FA was determined to be 2:1:4:3.•HT curing promotes the generation of hydration products and improves early strength.•The main hydration products are N-A-S-H gel, C-(A)-S-H gel and FS crystal. Lack of proper disposal of carbide slag (CS), soda residue (SR), and red mud (RM), which are alkaline solid wastes released from the production of acetylene, soda ash, and alumina, respectively, adversely affects the environment. This study synthesized a new low-carbon cementitious material using CS-SR-RM-fly ash (FA) as raw material and optimized its curing method.The influence of raw material composition and various curing systems on the mechanical properties and microstructure of specimens was analyzed using compressive strength, chloride ion consolidation, XRD, FTIR, and SEM-EDS. The optimum ratio of CS:SR:RM:FA was determined to be 2:1:4:3, and the compressive strength of 3/28 d at room temperature (RT) sealed curing reached 10.7/22.1 MPa. The alkaline environment created by CS-SR-RM facilitated the decomposition of active components in FA and RM, contributing to the formation of a stable three-dimensional network comprising N-A-S-H gel, C-(A)-S-H gel, and Friedel's salt crystal product. High-temperature (HT) curing at 80 °C for 8 h significantly enhanced early strength, with strength growth rates of up to 147.7/29.9% compared with RT sealed curing at 3/28 d. HT curing promoted the rapid and steady growth of hydration products, resulting in increased structural compactness and improved strength. The present study offers suggestions for reducing the environmental pollution caused by alkaline solid waste and developing new resource utilization means.