Sie befinden Sich nicht im Netzwerk der Universität Paderborn. Der Zugriff auf elektronische Ressourcen ist gegebenenfalls nur via VPN oder Shibboleth (DFN-AAI) möglich. mehr Informationen...
Magnetic pigments composed of SrxBa1-xFe12O19 were prepared using a modified Pechini method. The influence of the calcination temperature and the composition of the solid solution on the structural, colorimetric, and magnetic properties were investigated. XRD patterns showed pigments crystallizing in a magnetoplumbite-type structure after calcination above 900 °C. The formation of α-Fe2O3 as a secondary phase was also observed in some compositions. Raman and Mössbauer spectroscopy indicated the presence of Fe in different coordination sites, which strongly influenced the magnetic and colorimetric properties of the pigments. A brown colour was obtained for all the magnetic pigments, with a higher saturation when calcination was performed at 900 °C. A meaningful increase in saturation was attained for the sample with a Sr0·50Ba0·50Fe12O19 composition, which was related to the short-range disorder and occupancy of Fe3+ cations at different sites. The addition of Sr2+ (up to x = 0.50) to the solid solution improved the intensity of the brown colour by increasing the a* and b* colour coordinates and decreasing L*. Magnetic measurements revealed saturation magnetization values of 56.8 emu g−1 for BaFe12O19. Upon the addition of Sr2+, an increase in the ferromagnetic behaviour was observed for barium-containing pigments, which indicates the possibility of their use as magnetic pigments in high-density recording media or paints for construction.