Details

Autor(en) / Beteiligte

• Liao, Xiaoyuan
• Wang, Fan
• Wang, Yinzhi
• Cai, Yi
• Liu, Haitang
• Wang, Xuefeng
• Zhu, Yulei
• Chen, Lungang
• Yao, Yue
• Hao, Qinglan

Titel

Constructing Fe-based bi-MOFs for photo-catalytic ozonation of organic pollutants in Fischer-Tropsch waste water

Ist Teil von

• Applied surface science, 2020-04, Vol.509, p.145378, Article 145378

Ort / Verlag

Elsevier B.V

Erscheinungsjahr

2020

Link zum Volltext

Quelle

Elsevier ScienceDirect Journals Complete

Beschreibungen/Notizen

• [Display omitted] •The MIL-88A@MIL-88B photocatalyst was successfully prepared by internal extended growth method.•This bi-MOFs material is with larger surface area, adequate active sites, and strong interfacial coupling.•Fast FeIII/FeII conversion and catalyst’s recover.•Avoid the loss of Fe ions in the bi-MOFs structure.•h+ and O2− are the predominant active radicals. Fischer-Tropsch waste water (FTW) is with complex organic compositions, and is toxic/stinking odor. So far, FTW is very difficult to be treated in industry. In this work, Fe-based bi-MOFs heterojunctions, i.e., MIL-88A(Fe)@MIL-88B(Fe) are synthesized through internal extended growth of rod-like MIL-88A on spindle-like MIL-88B. The compositions, structure and characteristics are systematically investigated. By virtue of larger surface area, rich active sites and strong interfacial coupling, this bi-MOFs catalyst establish better h+-e− separation/transfer. As expected, this bi-MOFs hybrid materials shows remarkable photo-catalytic performance toward FTW remediation by the help of ozone. The COD removal in bi-MOFs/O3 system is 4.2 times higher than that of ozonation alone. Furthermore, h+, O2− and OH are the predominant active radicals for FTW remediation. Bi-MOFs displays acceptable stability after 5 cycles. This work provides a new way for photo-catalytic ozonation and may drive the development of MOFs-based photo-catalytic ozonation for waste water treatment, not limited in FTW.