Details

Autor(en) / Beteiligte

• Szakács-Schmidt, Anikó
• Kreisz, József
• Markó, Lászlo
• Nagy-Magos, Zsuzsa
• Takács, János

Titel

Iron(II) thiolates as reversible carbon monoxide carriers

Ist Teil von

• Inorganica Chimica Acta, 1992-08, Vol.198, p.401-405

Ort / Verlag

Elsevier B.V

Erscheinungsjahr

1992

Quelle

Elsevier Journal Backfiles on ScienceDirect (DFG Nationallizenzen)

Beschreibungen/Notizen

• Solutions of several iron(II) thiolato complexes in methanol, dimethylformamide or 2-ethoxyethanol reversibly absorb and release carbon monoxide at atmospheric pressure and 20–50 °C. Solutions of Fe(SPh) 2(H 2NCH 2CH 2NH 2) (CO) 2 and of an anionic complex tentatively formulated as [Fe 2(SPh) 5(CO) 4] − in 2-ethoxyethanol and of Fe(L-SCH 2CH(NH 2)COOEt) 2(CO) 2 in dimethylformamide were found to be most effective for the separation of CONe 2 gas mixtures.