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Direct TEM Observation of Phase Separation and Crystallization in Cu45Zr45Ag10 Metallic Glass
Ist Teil von
Acta metallurgica sinica : English letters, 2016-06, Vol.29 (6), p.538-545
Ort / Verlag
Beijing: The Chinese Society for Metals
Erscheinungsjahr
2016
Link zum Volltext
Quelle
SpringerLink
Beschreibungen/Notizen
The structural evolution of Cu
45
Zr
45
Ag
10
metallic glass was investigated by in situ transmission electron microscopy heating experiments. The relationship between phase separation and crystallization was elucidated. Nucleation and growth-controlled nanoscale phase separation at early stage were seen to impede nanocrystallization, while a coarser phase separation via aggregation of Ag-rich nanospheres was found to promote the precipitation of Cu-rich nanocrystals. Coupling of composition and dynamics heterogeneities was supposed to play a key role during phase separation preceding crystallization.