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The methanol-to-gasoline (MTG) process is an efficient way to produce liquid fuel. The academic basis of the coal-to-liquid process is described and two different synthesis processes are focused on: Fixed MTG process and Fluid Bed MTG process. Then, the superiority of the Fluid Bed MTG Process is pointed out relative to the Fixed MTG Process. In addition, the development of the coal-to-liquid technique in China is briefly summarized.