Details

Autor(en) / Beteiligte

• Srivastava, Rajendra M.
• Pereira, Maria C.
• Faustino, Wagner W. M.
• Coutinho, Kaline
• dos Anjos, Janaína V.
• de Melo, Sebastião J.

Titel

Synthesis, mechanism of formation, and molecular orbital calculations of arylamidoximes

Ist Teil von

• Monatshefte für Chemie, 2009-11, Vol.140 (11), p.1319-1324

Ort / Verlag

Vienna: Springer Vienna

Erscheinungsjahr

2009

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A simple and easy synthesis of ten arylamidoximes from arylnitriles and hydroxylamine is described. The formation of the arylamides has been observed to a much lesser extent in the present work. A new mechanism for the formation of arylamidoximes, as well as arylamides, from arylnitriles and hydroxylamine is suggested. Quantum mechanical calculations have been carried out to support this mechanism. The enthalpy of formation in conjunction with atomic charges of the reactants and intermediates helped to understand more about the generation of the products. Graphical Abstract