Details

Autor(en) / Beteiligte

• Ciobanu, Oxana
• Fuchs, Alexander
• Reinmuth, Matthias
• Lebkücher, Anna
• Kaifer, Elisabeth
• Wadepohl, Hubert
• Himmel, Hans-Jörg

Titel

Reactions between Boron and Magnesium Halides and the Bicyclic Guanidine hppH (1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidine): Guanidinates with New Structural Motifs

Ist Teil von

• ZAAC - Journal of Inorganic and General Chemistry, 2010-03, Vol.636 (3-4), p.543-550

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2010

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Herein we report on the synthesis and chemical properties of some binuclear and oligonuclear compounds of boron‐ and magnesium‐containing bridging guanidinate ligands. These species were prepared by reaction of the bicyclic guanidine hppH (hppH = 1,3,4,6,7,8‐hexahydro‐2H‐pyrimido[1,2‐a]pyrimidine) and BCl3, the diborane(4) B2Cl2(NMe2)2 or the Grignard compound MeMgBr. The experimental results are complemented by quantum chemical (DFT) calculations.