Details

Autor(en) / Beteiligte

• Yao, Jing-Cai
• Zhang, Li
• Wang, Yu-Fang
• Ma, Lu-Fang
• Wang, Li-Ya

Titel

Synthesis, Crystal Structure and Magnetic Behaviour of {[Co(dimb)2(H2O)2]·(NO3)2·(H2O)2}n

Ist Teil von

• Zeitschrift für anorganische und allgemeine Chemie (1950), 2008-08, Vol.634 (10), p.1648-1650

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2008

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The title complex {[Co(dimb)2(H2O)2]·(NO3)2·(H2O)2}n (1) (dimb = 1,3‐di(imidazol‐1‐ylmethyl)‐5‐methylbenzene) has been hydrothermally synthesized by the reaction of dimb with Co(NO3)2·6H2O in aqueous solution. The cobalt(II) atoms are linked by bridging dimb ligands to form 2D corrugated and wavy networks containing Co4(dimb)4 macrocyclic motifs. Two neighboring independent layers interlinked each other in a parallel fashion to construct three‐dimensional structure by O–H···O, N–H···O and C–H···O hydrogen bonds. Magnetic measurement shows the weak antiferromagnetic interaction with a one‐dimensional chain model in the range of 5–300 K, with J of –0.68 cm−1.