Details

Autor(en) / Beteiligte

• Son, Seung Uk
• Kim, Do Han
• Jung, Il Gu
• Chung, Young Keung
• Lee, Sueg-Geun
• Chun, Sung-Ho

Titel

Use of the Pauson-Khand reaction products as monomers in the palladium(II)-catalyzed homopolymerization and copolymerization of norbornene derivatives

Ist Teil von

• Journal of polymer science. Part A, Polymer chemistry, 2003-01, Vol.41 (1), p.76-83

Ort / Verlag

New York: Wiley Subscription Services, Inc., A Wiley Company

Erscheinungsjahr

2003

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• New norbornene derivatives synthesized from Pauson–Khand reaction products were homopolymerized and copolymerized with norbornene with an allyl–palladium complex as a catalyst. The ketone group was tolerated by the polymerization reaction. Monomers bearing protected alcohols were easily homopolymerized. Most of the homopolymers were soluble in tetrahydrofuran, CH2Cl2, toluene, and cyclohexane. As the steric bulkiness of the substituent increased, the chain length of the homopolymer decreased. Copolymers with a molecular weight of up to 153,800 were formed and were soluble in tetrahydrofuran, CH2Cl2, toluene, and diethyl ether. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 76–83, 2003 New norbornene derivatives synthesized from Pauson–Khand reaction products were homopolymerized and copolymerized with norbornene with allyl–palladium complex as a catalyst. Most of the homopolymers were soluble in tetrahydrofuran, CH2Cl2, toluene, and cyclohexane.