Details

Autor(en) / Beteiligte

• Flowers, W. T.
• Haszeldine, R. N.
• Janik, A.
• Lee, A. K.
• Marshall, P. G.
• Sedgwick, R. D.

Titel

Application of mass spectrometry to the study of fluoropolymers. III. Polyperfluorobut‐2‐yne

Ist Teil von

• Journal of polymer science. Part A-1, Polymer chemistry, 1972-12, Vol.10 (12), p.3497-3501

Erscheinungsjahr

1972

Quelle

Wiley Online Library Journals Frontfile Complete

Beschreibungen/Notizen

• Abstract Mass spectra of the volatile fractions from polyperfluorobut‐2‐yne have been obtained. The polymer appears to be thermally stable up to 300°C and molecules containing up to 12 monomer units have been identified. A regular structure is indicated by the mass spectrum which is characterized by unusually intense doubly charged ions. The endgroups are readily identified, and a conjugated polyolefin structure is indicated.