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1,2,3-Triazole-Incorporated Diacrylate Monomer for Free Radical Cyclopolymerization Through Large Ring Formation
Ist Teil von
Macromolecular chemistry and physics, 2011-05, Vol.212 (10), p.1050-1055
Ort / Verlag
Weinheim: WILEY-VCH Verlag
Erscheinungsjahr
2011
Link zum Volltext
Quelle
Wiley Online Library Journals
Beschreibungen/Notizen
A new 1,2,3‐triazole incorporated diacrylate monomer is designed for free radical cyclopolymerization through the formation of 11‐membered rings. NMR analysis on the cyclopolymers including 1H, 13C, DEPT‐135, and 1H–13C HMQC spectra support a high degree of cyclization. GPC profiles of the obtained cyclopolymers show unimodal distributions indicative of no chain branching reactions.
A new 1,2,3‐triazole incorporated diacrylate monomer is designed for free radical cyclopolymerization through the formation of eleven‐membered rings. Structural analysis of the cyclopolymers based on NMR analysis including 1H, 13C, DEPT‐135, and 1H–13C HMQC spectra supports a high degree of cyclization. GPC profiles of the cyclopolymers show unimodal distributions indicative of no chain branching reactions.