Details

Autor(en) / Beteiligte

• Li, Juan
• Zhao, Zhenwei
• Kazakov, Andrei
• Dryer, Frederick L.

Titel

An updated comprehensive kinetic model of hydrogen combustion

Ist Teil von

• International journal of chemical kinetics, 2004-10, Vol.36 (10), p.566-575

Ort / Verlag

New York: John Wiley & Sons, Inc

Erscheinungsjahr

2004

Quelle

Wiley Blackwell Single Titles

Beschreibungen/Notizen

• A comprehensively tested H2/O2 chemical kinetic mechanism based on the work of Mueller et al. 1 and recently published kinetic and thermodynamic information is presented. The revised mechanism is validated against a wide range of experimental conditions, including those found in shock tubes, flow reactors, and laminar premixed flame. Excellent agreement of the model predictions with the experimental observations demonstrates that the mechanism is comprehensive and has good predictive capabilities for different experimental systems, including new results published subsequent to the work of Mueller et al. 1, particularly high‐pressure laminar flame speed and shock tube ignition results. The reaction H + OH + M is found to be primarily significant only to laminar flame speed propagation predictions at high pressure. All experimental hydrogen flame speed observations can be adequately fit using any of the several transport coefficient estimates presently available in the literature for the hydrogen/oxygen system simply by adjusting the rate parameters for this reaction within their present uncertainties. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 566–575, 2004