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A simple one‐pot method for esterification
A one‐pot procedure for esterifications of primary, secondary and tertiary alcohols and of phenols in high yield is described. Reaction of oxalylchloride with dimethylformamide in a suitable solvent affords dimethylformamide imidechloride; addition of an acid to the suspension of this reagent furnishes an activated carboxy‐group derivative, which is then transformed to an ester by addition of pyridine and an alcohol ro a phenol. Reaction temperatures needed for esterification are low, usually 0° to room temperature, reaction times are short.