Details

Autor(en) / Beteiligte

• Ma, Ben
• Xia, Qi
• Wang, Deyang
• Jin, Ji‐Kang
• Li, Zekun
• Liang, Qiu‐Jiang
• Sun, Meng‐Ying
• Liu, Dongyi
• Liu, Li‐Juan
• Shu, Hui‐Xing
• Yang, Jun
• Li, Dan
• He, Jian

Titel

Back Cover: Metal‐Organic Framework Supported Copper Photoredox Catalysts for Iminyl Radical‐Mediated Reactions (Angew. Chem. Int. Ed. 21/2023)

Ist Teil von

• Angewandte Chemie (International ed.), 2023-05, Vol.62 (21), p.n/a

Erscheinungsjahr

2023

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A binap‐ligated copper iodide dimer embedded on a metal−organic framework (MOF) was designed as an effective photoredox catalyst by Dan Li, Jian He, and co‐workers in their Research Article (e202300233). Under visible‐light irradiation, this heterogenized copper(I) complex promotes multiple iminyl radical‐mediated reactions initiated by N−O bond cleavage, with significantly enhanced photocatalytic activity compared to its homogeneous counterparts. The use of a hydroxamic acid linker for post‐synthetic modification renders the catalyst recyclable.