Details

Autor(en) / Beteiligte

• Böttcher, Arnd
• Elias, Horst
• Müller, Lutz
• Paulus, Helmut

Titel

Oxygen Activation on Nickel(II)tetrahydrosalen Complexes with the Formation of Nickel(II)dihydrosalen Complexes

Ist Teil von

• Angewandte Chemie (International ed.), 1992-05, Vol.31 (5), p.623-625

Ort / Verlag

Zug: Hüthig & Wepf Verlag

Erscheinungsjahr

1992

Link zum Volltext

Quelle

Wiley Blackwell Single Titles

Beschreibungen/Notizen

• The oxidative dehydrogenation of only one CN bond in the [Ni(tetrahydrosalen)] complex 1 surprisingly affords the corresponding [Ni(dihydrosalen)] complex. This reaction is thus a rare example of the activation of oxygen by nickel complexes. The Ni atom in 1 has an almost square‐planar coordination geometry, and the two benzene rings are bent slightly upwards and downwards relative to the NiO2N2 plane.