Details

Autor(en) / Beteiligte

• Koch, Hans-Joachim
• Roesky, Herbert W.
• Bohra, Rakesh
• Noltemeyer, Mathias
• Schmidt, Hans-Georg

Titel

Cyclometallaborazines: Borazines with Metal Atoms as Ring Building Blocks: PhB(MeN)3(TiCl2)2

Ist Teil von

• Angewandte Chemie (International ed.), 1992-05, Vol.31 (5), p.598-599

Ort / Verlag

Zug: Hüthig & Wepf Verlag

Erscheinungsjahr

1992

Quelle

Wiley-Blackwell Journals

Beschreibungen/Notizen

• 75 years after the discovery of borazine by Stock et al., metal atoms could for the first time be introduced as ring components into the borazine framework. The compounds 2 and 3 are formed in the ratio 1:1 in 98% yield from 1 and TiCl4. As a result of strong intramolecular TiN interactions, 2 is not planar but can be described as a doubly edge‐bridged Ti2N2 tetrahedron.