Details

Autor(en) / Beteiligte

• Boese, Roland
• Bläser, Dieter
• Halterman, Ronald L.
• Vollhardt, K. Peter C.

Titel

First Case of Interannular, Possibly Electronically Transmitted, Asymmetric Induction in an Organometallic Compound

Ist Teil von

• Angewandte Chemie (International ed.), 1988-04, Vol.27 (4), p.553-555

Ort / Verlag

Zug: Hüthig & Wepf Verlag

Erscheinungsjahr

1988

Link zum Volltext

Quelle

Wiley Online Library Journals Frontfile Complete

Beschreibungen/Notizen

• Nucleophilic addition of alkynyllithium compounds Nu to the chiral cobaltocenium ion 1 leads to a mixture of 2 and 3 in a ring‐specific as well as a regio‐ and diastereoselective fashion, the attacking species approaching the substrate from the exo side with respect to the metal and the bottom cyclopentadienyl ring (R1, R2H, CH3).