Details

Autor(en) / Beteiligte

• Caruso, Tonino
• Feroci, Marta
• Inesi, Achille
• Orsini, Monica
• Scettri, Arrigo
• Palombi, Laura

Titel

Electrochemically Induced Addition Reactions in the Absence of Solvent and Supporting Electrolyte

Ist Teil von

• Advanced synthesis & catalysis, 2006-09, Vol.348 (14), p.1942-1947

Ort / Verlag

Weinheim: WILEY-VCH Verlag

Erscheinungsjahr

2006

Quelle

Wiley Online Library - AutoHoldings Journals

Beschreibungen/Notizen

• Solvent‐ and supporting electrolyte‐free electrolysis in a two‐compartment cell proved to be effective for the direct electroactivation of CH acid‐containing compounds vs. catalytic addition processes. Michael adducts (including quaternary carbon centres) and 2‐nitroalkanols were obtained in very good yields and selectivity on application of a catalytic amount of electricity under galvanostatic conditions.