Details

Autor(en) / Beteiligte

• Holmsen, Marte Sofie
• Nova, Ainara
• Øien-Ødegaard, Sigurd
• Heyn, Richard H
• Tilset, Mats

Titel

A highly asymmetric gold(III) η3‐allyl complex

Ist Teil von

• Angewandte Chemie (International ed.), 2020

Ort / Verlag

Wiley - VCH Verlag GmbH

Erscheinungsjahr

2020

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A highly asymmetric AuIII η3‐allyl complex has been generated by treating Au(η1‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf2. The resulting η3‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature 1H NMR suggest that the allyl ligand is highly fluxional.