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Preparation and characterization of barium strontium titanate/silicon nanoporous pillar array composite thin f'flms by a sol-gel method
Ist Teil von
矿物冶金与材料学报:英文版, 2012, Vol.19 (8), p.762-767
Erscheinungsjahr
2012
Quelle
SpringerLink
Beschreibungen/Notizen
Barium strontium titanate (Ba0.5Sr0.5TiO3, BST)/silicon nanoporous pillar array (Si-NPA) thin films were prepared by a spin-coating/annealing technique based on Si-NPA with micro/nano-structure. Both the isomer conversion of acetylacetone and the network structure combined by enol and Ti-alkoxide facilitate the formation of the BST sol and the subsequent crystallization. Before the perovskite BST begins to form, the intermediate phase (Ba, Sr)Ti2OsCO3 is found. The boundary between BST and Si-NPA is of clarity and little interface diffusion, disclosing that Si-NPA is an ideal template substrate in the preparation of multifunctional composite films.