Details

Autor(en) / Beteiligte

• Zhou, H. D
• Lumata, L. L
• Kuhns, P. L
• Reyes, A. P
• Choi, E. S
• Dalal, N. S
• Lu, J
• Jo, Y. J
• Balicas, L
• Brooks, J. S
• Wiebe, C. R

Titel

Ba3NbFe3Si2O14: A New Multiferroic with a 2D Triangular Fe3+ Motif

Ist Teil von

• Chemistry of materials, 2009-01, Vol.21 (1), p.156-159

Ort / Verlag

American Chemical Society

Erscheinungsjahr

2009

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Single crystals of the new multiferroic Ba3NbFe3Si2O14 have been synthesized and characterized via X-ray diffraction, magnetic susceptibility, NMR, and electric polarization measurements. The underlying topology of the Fe 3+ spins is composed of isolated triangular units stacked in 2D layers along the c-direction of the trigonal lattice. Magnetic susceptibility experiments verify the spin state of the iron moments (S = 5/2), and large antiferromagnetic interactions with θ = −190 K. A cusp in the susceptibility and lambda-like feature in the specific heat indicate a magnetic phase transition at T N = 26 K, resulting in a frustration index of f = 7. A significant amount of spin entropy is released at higher temperatures, suggestive of short-ranged magnetic correlations developing at 50 K (as evidenced by features in the specific heat and thermal conductivity). The development of a spontaneous electric polarization below 26 K verifies that Ba3NbFe3Si2O14 is a multiferroic.